Hydrolysis protection and sintering of aluminum nitride powders with yttria nanofilms
نویسندگان
چکیده
Aluminum nitride (AlN) is a promising material for electronic substrates and heat sinks. However, AlN powders react with water that adversely affects final part properties necessitates processing in organic solvents, increasing the cost of parts. Small quantities yttrium oxide (Y2O3) are commonly added to particles enable liquid phase sintering. To mitigate reaction water, particle atomic layer deposition (ALD) was used coat conformal films Y2O3 prior densification powder processing. When were coated 6 nm thick amorphous Y2O3, hydrolysis significantly suppressed over 48 h, demonstrating nanofilms on act as barrier coating an aqueous solution. addition by ALD sintered high relative densities (≥90% theoretical) after sintering at 1800°C 50 min.
منابع مشابه
Sintering Behaviors of Carbon Nanotubes—Aluminum Composite Powders
Carbon nanotubes (CNTs) are promising reinforcements for fabricating aluminum (Al) matrix composites with outstanding properties. The understanding of the consolidation process of CNT–Al composite powders plays a significant role in achieving high performances of bulk composites. In this study, an advanced consolidation technique of spark plasma sintering (SPS) was used to fabricate CNT–Al comp...
متن کاملSintering of Fine Oxide Powders: II, Sintering Mechanisms
Conventional and new sintering mechanisms have been porous compacts is well-known in the ceramic literature. However, several reports have been presented recently that investigated using fine powders of CeO2 and Y2O3 of excellent sinterability. We have verified the validity of Herring’s show that particle/grain size can remain essentially constant up to a density of 92%, and such a resistance t...
متن کاملMicrowave Sintering of Aluminum Alloys
Until 2000 almost all research in the microwave sintering area was confined to non-metallic materials. However, after the first report by Penn State in 1999 on full sintering of steel powders in microwave, now in the last few years there has been increasing interest in applying microwave energy for processing of variety of metallic materials. The present study is an extension of this work and r...
متن کاملTheoretical comparison of thermodynamic parameters, NMR analysis, electronic properties of Boron Nitride and Aluminum Nitride nanotubes
In this research, geometrical structures of armchair single walled boron nitride nanotube (SWBNNT) and armchair single walled aluminum nitride nanotube (SWAlNNT) were optimized by Density Functional Theory (DFT) in the gas phase, both having the same length of 5 angstrom and n=9, m=9. B3LYP/6-31G* level of theory have been used to determine and compare electronic properties, n...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the American Ceramic Society
سال: 2022
ISSN: ['0002-7820', '1551-2916']
DOI: https://doi.org/10.1111/jace.18310